Pseudotetrahedral rhodium(I) complexes.
نویسندگان
چکیده
A combination of four-electron donors, such as alkynes, with strongly donating and strong-field scorpionate ligands is appropriate to create pseudotetrahedral rhodium(I) environments, as found in [Rh(PhBP3 )(HCCPh)], which promotes HC bond activation and CC coupling reactions under very smooth conditions.
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ورودعنوان ژورنال:
- Chemistry
دوره 20 10 شماره
صفحات -
تاریخ انتشار 2014